Mata Kuliah KI5031 - 2024

Kode Mata KuliahKI5031 / 3 SKS
Penyelenggara205 - Kimia / FMIPA
KategoriKuliah
Bahasa IndonesiaEnglish
Nama Mata KuliahKatalisisCatalysis
Bahan Kajian
  1. Konsep katalis, reaksi terkatalisis, dan evaluasi performa katalis.
  2. Karakter ligan dalam kendali elektronik dan struktur (vibrasi karbonil Ni(CO)3L vs Tolman angle).
  3. Tahapan reaksi organologam (adisi oksidatif; eliminasi reduktif; beta-H eliminasi; penyisipan olefin; penyipan karbonil)
  4. Penyangga katalis (model imobilisasi kompleks logam aktif)
  5. Polimerisasi olefin (ziegler-natta; metallocene; post metallocene)
  6. Reaksi metathesis dan ligan karbena (karbena singlet/triplet)
  7. Reaksi cross-coupling (PEPPSI catalysts)
  8. Reaksi epoksidasi (mekanisme Sharpless)
  9. Reaksi isomerisasi (mekanisme alkil vs alil)
  10. Reaksi hidrogenasi dan transfer hidrogen
  11. Reaksi karbonilasi
  12. Reaksi Fischer Tropsch
  1. Concepts of catalysis, catalyzed reactions, and catalyst performance evaluation
  2. Ligand characteristics in electronic and structural control (Ni(CO)₃L carbonyl vibrations vs Tolman angle)
  3. Organometallic reaction steps (oxidative addition; reductive elimination; β-hydride elimination; olefin insertion; carbonyl insertion)
  4. Catalyst supports (models for immobilization of active metal complexes)
  5. Olefin polymerization (Ziegler–Natta; metallocene; post-metallocene catalysts)
  6. Metathesis reactions and carbene ligands (singlet/triplet carbenes)
  7. Metathesis reactions and carbene ligands (singlet/triplet carbenes)
  8. Epoxidation reactions (Sharpless mechanism)
  9. Isomerization reactions (alkyl vs allyl mechanisms)
  10. Hydrogenation and hydrogen transfer reactions
  11. Carbonylation reactions
  12. Fischer–Tropsch reactions
Capaian Pembelajaran Mata Kuliah (CPMK)
  1. Mampu memahami peran ligan spektator/aktor dalam kendali elektronik logam pusat atau kendali struktur katalis pada senyawa kompleks dan menggunakannya pada usulan desain katalis berbasis modifikasi ligan selain pilihan jenis logam pusat.
  2. Mampu mengusulkan siklus katalitik yang mungkin dilewati oleh suatu tahapan reaksi terkatalisis logam transisi.
  3. Mampu memahami usulan siklus katalitik yang dipaparkan dalam suatu publikasi ilmiah katalisis (dari sumber ACS, RSC, Wiley, Elsevier) disertai pemahaman prediksi tahapan penentu laju jika data kinetika pendukung tersedia dalam literatur.
  1. Able to understand the role of spectator/active ligands in the electronic control of the central metal or structural control of catalysts in complex compounds, and to apply this understanding in the design of catalysts through ligand modification, beyond just the choice of the central metal.
  2. Able to propose possible catalytic cycles that may occur in a given transition-metal-catalyzed reaction step.
  3. Able to comprehend proposed catalytic cycles presented in scientific publications on catalysis (from ACS, RSC, Wiley, Elsevier), including the ability to predict rate-determining steps when supporting kinetic data are available in the literature.
Metode PembelajaranCeramah; Diskusi; PresentasiLectures; Discussions; Presentation
Modalitas PembelajaranLuring SinkronSynchronous In-Person Sessions
Jenis NilaiABCDE
Metode PenilaianUTS dan UAS Penilaian Kuliah: UTS 50%, UAS 50%Midterm Examinations and Final Examinations Course assessment: midterm examination 50%, final examination 50%
Catatan Tambahan