Bahan Kajian | - Riviu dipercepat hukum termodinamika I, II, dan III
- Persamaan keadaan (gas ideal, virial, dan kubik/EOS)
- Faktor asentrik dan kemampatan (compressibility)
- Konsep fugasitas sistem non ideal
- Aturan pencampuran sistem multikomponen
- Kriteria kesetimbangan fasa; perhitungan kesetimbangan fasa menggunakan persamaan kubik dan korelasi ;
- Aplikasi sistem kesetimbangan uap-cair: larutan ideal (aturan Lewis-Randall, hukum/model Raoult dan hukum Henry) dan larutan tak ideal (koefisien aktifitas, efek pencampuran dan fungsi ekses, model Raoult termodifikasi)
- Perhitungan koefisien aktifitas menggunakan korelasi Wuhl, Redlich-Kister, van Laar, Margules, Wilson, ASOG, NRTL, UNIQUAC, dan/atau UNIFAC
- Nisbah kesetimbangan uap-cair menurut Chao-Seader, BWRS dan grafik GPA, dan parameter tekanan konvergensi.
- Kesetimbangan reaksi sistem ideal dan tak ideal multireaksi dan/atau multifasa
| - Accelerated review of the laws of thermodynamics I, II, and III
- Equations of state (ideal gas, virial, and cubic/EOS)
- Accentric factor and compressibility
- Concept of fugacity of non-ideal systems
- Multicomponent system mixing rules
- Phase equilibrium criteria; phase equilibrium calculations using cubic equations and correlations;
- Applications of vapor-liquid equilibrium systems: ideal solutions (Lewis-Randall rule, Raoult's law/model and Henry's law) and non-ideal solutions (activity coefficient, mixing effect and excess function, modified Raoult's model).
- Activity coefficient calculation using Wuhl, Redlich-Kister, van Laar, Margules, Wilson, ASOG, NRTL, UNIQUAC, and/or UNIFAC correlations.
- Chao-Seader vapor-liquid equilibrium ratio, BWRS and GPA charts, and convergence pressure parameters.
- Reaction equilibrium of multireaction and/or multiphase ideal and non-ideal systems
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Capaian Pembelajaran Mata Kuliah (CPMK) | - Mampu menyusun persamaan konservasi dan membandingkan efisiensi untuk unit operasi Teknik Kimia dengan mempertimbangkan hukum Termodinamika I, II, dan III.
- Mampu memprediksi sifat termodinamika fluida gas nyata menggunakan persamaan keadaan kompleks multikomponen.
- Mampu memprediksi sifat termodinamika fasa gas dan fasa cair menggunakan persamaan model kesetimbangan-fasa kompleks multikomponen.
- Mampu memprediksi koordinat reaksi dan komposisi reaksi kesetimbangan pada kondisi nyata multireaksi dan/atau multifasa.
| - Able to compile conservation equations and compare efficiencies for Chemical Engineering operating units by considering the laws of Thermodynamics I, II, and III.
- Able to predict the thermodynamic properties of real gaseous fluids using multicomponent complex equations of state.
- Able to predict thermodynamic properties of gas phase and liquid phase using multicomponent complex phase-equilibrium model equations.
- Able to predict reaction coordinates and composition of equilibrium reactions under real conditions of multireaction and/or multiphase.
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Metode Pembelajaran | diskusi kelompok, simulasi, studi kasus, pembelajaran berbasis proyek, pembelajaran berbasis masalah | group discussion, simulation, case study, project-based learning, problem-based learning |
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