| Kode Mata Kuliah | KI4032 / 3 SKS |
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| Penyelenggara | 105 - Chemistry / FMIPA |
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| Kategori | Lecture |
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| Bahasa Indonesia | English |
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| Nama Mata Kuliah | Pengantar Katalisis | Introduction to Catalysis |
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| Bahan Kajian | - Reaksi terkatalisis/terinhibisi; logam aktif; ligan spektator/ligan aktor; penyangga
- Performa katalitik (konversi, selektifitas, hasil, TON, TOF)
- Tahapan reaksi organologam (adisi oksidatif; eliminasi reduktif; beta-H eliminasi; penyisipan olefin; penyipan karbonil)
- Polimerisasi olefin (ziegler-natta; metallocene; post metallocene)
- Reaksi metathesis dan ligan karbena (karbena singlet/triplet)
- Reaksi epoksidasi (mekanisme Sharpless)
- Reaksi isomerisasi (mekanisme alkil vs alil)
- Reaksi hidrogenasi dan transfer hidrogen
- Reaksi karbonilasi
| - Catalyzed/Inhibited Reactions; Active Metals; Spectator/Actor Ligands; Supports
- Catalytic Performance (conversion, selectivity, yield, TON, TOF)
- Steps in Organometallic Reactions (oxidative addition; reductive elimination; beta-H elimination; olefin insertion; carbonyl insertion)
- Olefin Polymerization (Ziegler-Natta; metallocene; post-metallocene)
- Metathesis Reactions and Carbene Ligands (singlet/triplet carbenes)
- Epoxidation Reactions (Sharpless mechanism)
- Isomerization Reactions (alkyl vs allyl mechanism)
- Hydrogenation and Hydrogen Transfer Reactions
- Carbonylation Reactions
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| Capaian Pembelajaran Mata Kuliah (CPMK) | - Mampu memahami peran ligan spektator/aktor dalam kendali elektronik logam pusat atau kendali struktur katalis pada senyawa kompleks dan menggunakannya pada usulan desain katalis berbasis modifikasi ligan selain pilihan jenis logam pusat.
- Mampu mengusulkan siklus katalitik yang mungkin dilewati oleh suatu tahapan reaksi terkatalisis logam transisi
- Mampu memahami usulan siklus katalitik yang dipaparkan dalam suatu publikasi ilmiah katalisis (dari sumber ACS, RSC, Wiley, Elsevier) disertai pemahaman prediksi tahapan penentu laju jika data kinetika pendukung tersedia dalam literatur.
| - Able to understand the role of spectator/actor ligands in controlling the electronic properties of the central metal or the structure of catalysts in complex compounds and use this knowledge to propose catalyst designs based on ligand modifications besides the choice of the central metal type.
- Able to propose possible catalytic cycles that a transition metal-catalyzed reaction step may undergo.
- Able to understand proposed catalytic cycles presented in scientific catalysis publications (from sources such as ACS, RSC, Wiley, Elsevier) along with understanding the prediction of rate-determining steps if supporting kinetic data are available in the literature.
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| Metode Pembelajaran | Ceramah; Diskusi; Presentasi | Lectures; Discussions; Presentations |
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| Modalitas Pembelajaran | Luring Sinkron | Synchronous Offline |
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| Jenis Nilai | ABCDE |
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| Metode Penilaian | UTS dan UAS | Midterm Exam and Final Exam |
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| Catatan Tambahan | | |
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